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1

Industrial Synthesis of (+)-cis-Methyl Dihydrojasmonate by Enantioselective Catalytic Hydrogenation; Identification of the Precatalyst [Ru((−)-Me-DuPHOS)(H)(η6-1,3,5-cyclooctatriene)](BF4)

Daniel A. Dobbs, Koenraad P. M. Vanhessche, Eric Brazi, Valentin Rautenstrauch, Jean-Yves Lenoir, Jean-Pierre Genêt, Jason Wiles, Steven H. Bergens

Journal:

Angewandte Chemie International Edition

Year:

2000

Language:

english

File:

PDF, 100 KB

english, 2000

2

2-Cyclopentenones from 1-ethynyl-2-propenyl acetates

Rautenstrauch, Valentin

Journal:

Journal of Organic Chemistry

Year:

1984

Language:

english

File:

PDF, 969 KB

english, 1984

3

Vinyl migration in Wittig rearrangements

Rautenstrauch, Valentin, Buchi, George, Wuest, Hans

Journal:

Journal of the American Chemical Society

Year:

1974

Language:

english

File:

PDF, 669 KB

english, 1974

4

Industrielle Synthese von (+)-cis-Methyldihydrojasmonat durch enantioselektive katalytische Hydrierung; Identifizierung des Präkatalysators [Ru((−)-Me-DuPHOS)(H)(η6-1,3,5-cyclooctatrien)](BF4)

Daniel A. Dobbs, Koenraad P. M. Vanhessche, Eric Brazi, Valentin Rautenstrauch, Jean-Yves Lenoir, Jean-Pierre Genêt, Jason Wiles, Steven H. Bergens

Journal:

Angewandte Chemie

Year:

2000

Language:

german

File:

PDF, 89 KB

german, 2000

5

Ein flexibler und effizienter Zugang zu aktiven und wohldefinierten Katalysatoren des Typs [Ru(bisphosphan)(H)(solvens)3](BF4)

Jason A. Wiles, Steven H. Bergens, Koenraad P. M. Vanhessche, Daniel A. Dobbs, Valentin Rautenstrauch

Journal:

Angewandte Chemie

Year:

2001

Language:

german

File:

PDF, 124 KB

german, 2001

6

Ein flexibler und effizienter Zugang zu aktiven und wohldefinierten Katalysatoren des Typs [Ru(bisphosphan)(H)(solvens)3](BF4)

Jason A. Wiles, Steven H. Bergens, Koenraad P. M. Vanhessche, Daniel A. Dobbs, Valentin Rautenstrauch

Journal:

Angewandte Chemie

Year:

2001

Language:

german

File:

PDF, 32 KB

german, 2001

7

A Versatile and High-Yield Route to Active and Well-Defined Catalysts [Ru(bisphosphane)(H)(solvent)3](BF4)

Jason A. Wiles, Steven H. Bergens, Koenraad P. M. Vanhessche, Daniel A. Dobbs, Valentin Rautenstrauch

Journal:

Angewandte Chemie International Edition

Year:

2001

Language:

english

File:

PDF, 135 KB

english, 2001

8

A Versatile and High-Yield Route to Active and Well-Defined Catalysts [Ru(bisphosphane)(H)(solvent)3](BF4)

Jason A. Wiles, Steven H. Bergens, Koenraad P. M. Vanhessche, Daniel A. Dobbs, Valentin Rautenstrauch

Journal:

Angewandte Chemie International Edition

Year:

2001

Language:

english

File:

PDF, 32 KB

english, 2001

9

Vinyllithium und 1,4-Dilithiobutan aus Äthylen und Lithium

Dr. Valentin Rautenstrauch

Journal:

Angewandte Chemie

Year:

1975

Language:

german

File:

PDF, 250 KB

german, 1975

10

Carbonylierung von Lithium-monoalkylamiden zu N-Lithio(alkyl)formamiden

Dr. Valentin Rautenstrauch, Michel Joyeux

Journal:

Angewandte Chemie

Year:

1979

Language:

german

File:

PDF, 263 KB

german, 1979

11

Carbonylierung von Lithium-dialkylamiden zu Carbamoyllithium-Derivaten

Dr. Valentin Rautenstrauch, Michel Joyeux

Journal:

Angewandte Chemie

Year:

1979

Language:

german

File:

PDF, 265 KB

german, 1979

12

Tripropylcarbazoyllithium

Dr. Valentin Rautenstrauch, Dr. François Delay

Journal:

Angewandte Chemie

Year:

1980

File:

PDF, 305 KB

1980

13

2-Pentylcyclopent-2-en-1-on durch katalytische Pauson-Khand-Reaktion

Prof. Dr. Valentin Rautenstrauch, Patrick Mégard, José Conesa, Dr. Wilhelm Küster

Journal:

Angewandte Chemie

Year:

1990

File:

PDF, 383 KB

1990

14

Enantioselective Synthesis. Natural Products from Chiral Terpenes. Von Tse-Lok Ho. Wiley, Chichester, 1992. XII, 324 S., geb. 56.00 £ – ISBN 0-471-54819-7

Valentin Rautenstrauch

Journal:

Angewandte Chemie

Year:

1993

Language:

german

File:

PDF, 312 KB

german, 1993

15

Vinyllithium and 1,4-Dilithiobutane from Ethylene and Lithium

Dr. Valentin Rautenstrauch

Journal:

Angewandte Chemie International Edition

Year:

1975

Language:

english

File:

PDF, 226 KB

english, 1975

16

Carbonylation of Lithium Monoalkylamides to Give N-Lithio(alkyl)formamides

Dr. Valentin Rautenstrauch, Dr. Michel Joyeux

Journal:

Angewandte Chemie International Edition

Year:

1979

Language:

english

File:

PDF, 246 KB

english, 1979

17

Carbonylation of Lithium Dialkylamides to Give Carbamoyllithiums

Dr. Valentin Rautenstrauch, Dr. Michel Joyeux

Journal:

Angewandte Chemie International Edition

Year:

1979

Language:

english

File:

PDF, 356 KB

english, 1979

18

Tripropylcarbazoyllithium

Dr. Valentin Rautenstrauch, Dr. Francois Delay

Journal:

Angewandte Chemie International Edition

Year:

1980

Language:

english

File:

PDF, 317 KB

english, 1980

19

2-Pentylcyclopent-2-en-1-one by Catalytic Pauson-Khand Reaction

Prof. Dr. Valentin Rautenstrauch, Patrick Mégard, José Conesa, Dr. Wilhelm Küster

Journal:

Angewandte Chemie International Edition

Year:

1990

Language:

english

File:

PDF, 477 KB

english, 1990

20

Book Review: Enantioselective Synthesis. Natural Products from Chiral Terpenes. By Tse-Lok Ho

Valentin Rautenstrauch

Journal:

Angewandte Chemie International Edition

Year:

1993

Language:

english

File:

PDF, 311 KB

english, 1993

21

Hydrogenation versus Transfer Hydrogenation of Ketones: Two Established Ruthenium Systems Catalyze Both

Valentin Rautenstrauch, Xuân Hoang-Cong, Raphaël Churlaud, Kamaluddin Abdur-Rashid, Robert H. Morris

Journal:

Chemistry - A European Journal

Year:

2003

Language:

english

File:

PDF, 280 KB

english, 2003

22

ChemInform Abstract: A New Synthesis of Methyl 3-Oxo-2-pentyl-1-cyclopentene-1-acetate.

Khushrav Crawford, Valentin Rautenstrauch, Arnold Uijttewaal

Journal:

Year:

2001

File:

PDF, 27 KB

2001

23

Modellreaktionen zur Biosynthese von Verbindungen der Damascon-Reihe und ihre präparative Anwendung

Günther Ohloff, Valentin Rautenstrauch, Karl H. Schulte-Elte

Journal:

Helvetica Chimica Acta

Year:

1973

File:

PDF, 762 KB

1973

24

Circulardichroismus. 62. Mitteilung. Chiroptische Eigenschaften einiger Trimethylcyclohexen-Derivate: Die Jonone, Irone und Abszisinsäuren

Günther Ohloff, Eberhard Otto, Valentin Rautenstrauch, Günther Snatzke

Journal:

Helvetica Chimica Acta

Year:

1973

File:

PDF, 594 KB

1973

25

Controlled Allylic Transformations via the Meisenheimer Rearrangement

Valentin Rautenstrauch

Journal:

Helvetica Chimica Acta

Year:

1973

Language:

english

File:

PDF, 1.05 MB

english, 1973

26

Preference for Syn Ene Additions of 1O2 to Trisubstituted, Acyclic Olefins

Karl H. Schulte-Elte, Bernard L. Muller, Valentin Rautenstrauch

Journal:

Helvetica Chimica Acta

Year:

1978

Language:

english

File:

PDF, 433 KB

english, 1978

27

Alkali Metal/Ammonia Reductions of Ketones Should Be Run in the Presence of Ammonium Ion

Valentin Rautenstrauch, Bruno Willhalm, Walter Thommen, Ulrich Burger

Journal:

Helvetica Chimica Acta

Year:

1981

Language:

english

File:

PDF, 1.83 MB

english, 1981

28

The Stereochemical Outcomes – the Isoborneol/Borneol Ratios – in Lithium, Sodium and Potassium/Ammonia Reductions without a Proton Source of the Enantiomers and the Racemate of Camphor Differ Strongly

Valentin Rautenstrauch

Journal:

Helvetica Chimica Acta

Year:

1982

Language:

english

File:

PDF, 318 KB

english, 1982

29

On the Stereochemistry of Irones

Valentin Rautenstrauch, Bruno Willhalm, Walter Thommen, Güther Ohloff

Journal:

Helvetica Chimica Acta

Year:

1984

Language:

english

File:

PDF, 385 KB

english, 1984

30

Singlet-Oxygen Ene Reactions of (E)-4-Propyl[1,1,-2H3]oct-4-ene. Short Communication

Valentin Rautenstrauch, Walter Thommen, Karl H. Schulte-Elte

Journal:

Helvetica Chimica Acta

Year:

1986

Language:

english

File:

PDF, 323 KB

english, 1986

31

Potassium Carboxylates by Direct Carbonylation of Potassium Alkoxides

Valentin Rautenstrauch

Journal:

Helvetica Chimica Acta

Year:

1987

Language:

english

File:

PDF, 425 KB

english, 1987

32

2,2′-Bifurylidene-5,5′-diones, Coumarins, 3a, 7a-dihydro-1H-inden-1-ones, and 5H-furo[3,2-b]pyran-5-ones from propyne and carbon monoxide

Valentin Rautenstrauch, Patrick Mégard, Betty Gamper, Bernadette Bourdin, Eric Walther, Gerald Bernardinelli

Journal:

Helvetica Chimica Acta

Year:

1989

Language:

english

File:

PDF, 895 KB

english, 1989

33

A Short Synthesis of (±)-Muscone

Valentin Rautenstrauch, Roger L. Snowden, Simon M. Linder

Journal:

Helvetica Chimica Acta

Year:

1990

Language:

english

File:

PDF, 412 KB

english, 1990

34

Enantiomeric Purities of (R)- and (S)-Camphors from the Chiral Pool and High Enantiomeric Purities in General

Valentin Rautenstrauch, Mikael Lindström, Bernadette Bourdin, Jane Curie, Esther Oliveros

Journal:

Helvetica Chimica Acta

Year:

1993

Language:

english

File:

PDF, 651 KB

english, 1993

35

Ketone dianions, ketone-ketyl coupling, and possible reaction-during-mixing effects in alkali metal/ammonia reductions of saturated ketones

Valentin Rautenstrauch

Journal:

Year:

1988

Language:

english

File:

PDF, 397 KB

english, 1988

36

NMR-spektren von cycloprop(a) acenaphthylenen

Valentin Rautenstrauch, Frank Wingler

Journal:

Tetrahedron Letters

Year:

1965

Language:

german

File:

PDF, 150 KB

german, 1965

37

Pd(II)-mediated coupling of 1,1-dimethyl-2-propynyl acetate with itself and 1-decene

Valentin Rautenstrauch

Journal:

Tetrahedron Letters

Year:

1984

Language:

english

File:

PDF, 108 KB

english, 1984

38

Additions and Corrections - Disproportionation of Saturated Alkali Metal Ketyls to Give Enolates and Alcoholates: a General Reaction That Has Been Overlooked

Rautenstrauch, Valentin, Geoffroy, Michel

Journal:

Journal of the American Chemical Society

Year:

1977

Language:

english

File:

PDF, 263 KB

english, 1977

39

Treating camphors with potassium in liquid ammonia leads to a double-Horeau duplication

Rautenstrauch, Valentin, Megard, Patrick, Bourdin, Bernadette, Furrer, Anton

Journal:

Journal of the American Chemical Society

Year:

1992

Language:

english

File:

PDF, 2.11 MB

english, 1992

40

High yield generation of a persistent, saturated lithium ketyl in solution. Characteristic reactions and identification by electron spin resonance

Rautenstrauch, Valentin, Geoffroy, Michel

Journal:

Journal of the American Chemical Society

Year:

1976

Language:

english

File:

PDF, 381 KB

english, 1976

41

Key Enantioselective Hydrogenation Steps in the Syntheses of Two Renin Inhibitors: Missing Origin and Incorrect Description

Rautenstrauch, Valentin

Journal:

Organic Process Research & Development

Year:

2012

Language:

english

File:

PDF, 132 KB

english, 2012

42

Disproportionation of saturated alkali metal ketyls to give enolates and alcoholates: a general reaction that has been overlooked

Rautenstrauch, Valentin, Geoffroy, Michel

Journal:

Journal of the American Chemical Society

Year:

1977

Language:

english

File:

PDF, 926 KB

english, 1977

43

Preference for the syn ene additions of 1O2 to 1-methylcycloalkenes. Correlation with ground-state geometry

Schulte-Elte, Karl H., Rautenstrauch, Valentin

Journal:

Journal of the American Chemical Society

Year:

1980

Language:

english

File:

PDF, 366 KB

english, 1980

44

Endo-selectivity and kinetic control in alkali metal?NH3?NH4 + reductions of bicyclo[2.2.1]heptan-2-ones

Rautenstrauch, Valentin

Journal:

Journal of the Chemical Society Chemical Communications

Year:

1986

Language:

english

File:

PDF, 277 KB

english, 1986

45

Transformation of the geraniol skeleton into the fragranol and grandisol skeletons

Rautenstrauch, Valentin

Journal:

Journal of the Chemical Society Chemical Communications

Year:

1978

Language:

english

File:

PDF, 183 KB

english, 1978

46

A New Synthesis of Methyl 3-Oxo-2-pentyl-1-cyclopentene-1-acetate

Crawford, Khushrav, Rautenstrauch, Valentin, Uijttewaal, Arnold

Journal:

Year:

2001

Language:

english

File:

PDF, 34 KB

english, 2001

47

ChemInform Abstract: VINYLLITHIUM UND 1,4-DILITHIOBUTAN AUS AETHYLEN UND LITHIUM

RAUTENSTRAUCH, VALENTIN

Journal:

Chemischer Informationsdienst

Year:

1975

File:

PDF, 105 KB

1975

48

ChemInform Abstract: CIRCULARDICHROISMUS 62. MITT. CHIROPTISCHE EIGENSCHAFTEN EINIGER TRIMETHYLCYCLOHEXEN-DERIVATE, JONONE, IRONE UND ABSZISINSAEUREN

OHLOFF, GUENTHER, OTTO, EBERHARD, RAUTENSTRAUCH, VALENTIN, SNATZKE, GUENTHER

Journal:

Chemischer Informationsdienst

Year:

1973

File:

PDF, 103 KB

1973

49

ChemInform Abstract: MODELLREAKTIONEN ZUR BIOSYNTHESE VON VERBINDUNGEN DER DAMASCON-REIHE UND IHRE PRAEPARATIVE ANWENDUNG

OHLOFF, GUENTHER, RAUTENSTRAUCH, VALENTIN, SCHULTE-ELTE, KARL H.

Journal:

Chemischer Informationsdienst

Year:

1973

File:

PDF, 232 KB

1973

50

ChemInform Abstract: VINYL MIGRATION IN WITTIG REARRANGEMENTS

RAUTENSTRAUCH, VALENTIN, BUECHI, GEORGE, WUEEST, HANS

Journal:

Chemischer Informationsdienst

Year:

1974

File:

PDF, 202 KB

1974

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